The 3A Band System in the Spectrum of the 13C16O Molecule.
| dc.contributor.author | Hakalla, Rafał | |
| dc.contributor.author | Kępa, Ryszard | |
| dc.contributor.author | Rytel, Marek | |
| dc.contributor.author | Zachwieja, Mirosław | |
| dc.date.accessioned | 2014-11-20T09:20:42Z | |
| dc.date.available | 2014-11-20T09:20:42Z | |
| dc.date.issued | 1999 | |
| dc.description.abstract | In the emission spectrum of the carbon monoxide 13C16O isotopic molecule three bands comprising about 1820 lines of the 3A band system (c3Π-a3Π) were recorded and analyzed. The 0-0 and 0-1 bands of this system were photographed for the first time and the 0-2 band was rephotographed by using methods of conventional high-resolution spectroscopy. The result of the rotational band analysis includes expanding of the spectrum interpretation up to J = 25 as well as the identification of four previously unobserved branches P13, R13, P31, and R31. Because of strong perturbations in the c3Π (ν = 0) state, the calculation of the rovibronic structure constants was performed only for the lower a3Π state. By using a calculation based on a nonlinear least-squares method, an effective Hamiltonian of Brown [J. M. Brown, E. A. Colbourn, J. K. G. Watson, and F. D. Wayne, J. Mol. Spectrosc. 74, 294-318 (1979)] and a separative procedure proposed by Curl-Dane-Watson [R. F. Curl and C. B. Dane, J. Mol. Spectrosc. 128, 406-412 (1988); J. K. G. Watson, J. Mol. Spectrosc. 138, 302-308 (1989)], it was possible to derive the rotational structure constants for the ν = 0, 1, and 2 levels for the a3Π state in the 13C16O isotopic molecule. Term values for the C3Π (ν = 0) level and the equilibrium molecular constants for the a3Π state also are reported. © 1999 Academic Press. | pl_PL.UTF-8 |
| dc.identifier.citation | J. Mol. Spectrosc. 197, 199 – 211 (1999). | pl_PL.UTF-8 |
| dc.identifier.issn | 00222852 | |
| dc.identifier.uri | http://repozytorium.ur.edu.pl/handle/item/758 | |
| dc.language.iso | eng | pl_PL.UTF-8 |
| dc.publisher | Academic Press (Journal of Molecular Spectroscopy) | pl_PL.UTF-8 |
| dc.subject | High resolution molecular spectroscopy | pl_PL.UTF-8 |
| dc.subject | carbon monoxide | |
| dc.subject | the 3A band system | |
| dc.subject | 13C16O | |
| dc.title | The 3A Band System in the Spectrum of the 13C16O Molecule. | pl_PL.UTF-8 |
| dc.type | article | pl_PL.UTF-8 |