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Extended analysis of the Ångström band system (B1Σ+ - A1Π) in the rare12C17O isotopologue.

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Show simple item record Hakalla, Rafał Szajna, Wojciech Zachwieja, Mirosław 2014-11-19T10:05:46Z 2014-11-19T10:05:46Z 2012-11
dc.identifier.citation J. Phys. B At. Mol. Opt. Phys., 2012, 45, 215102 pl_PL.UTF-8
dc.identifier.issn 09534075
dc.description.abstract The Ångström band system (B 1Σ + A 1Π), so far unobserved in the rare 12C 17O isotopologue, was obtained under high resolution as an emission spectrum using high accuracy dispersive optical spectroscopy. In total, 200 transition wave numbers belonging to the 0-1 and 0-2 bands were precisely measured and rotationally analysed. The obtained result was the merged rotational constants B 0 = 1.8988823(41)cm 1 and D 0 = 6.4283(26) × 10 6 cm 1 for the B 1Σ + Rydberg state as well as the individual rotational constants B 1 = 1.54088(12)cm 1, D 1 = 6.950(87) × 10 6cm 1, B 2 = 1.519292(69)cm 1, D 2 = 8.22(16) × 10 6cm 1 for the A 1Π state in the 12C 17O isotopologue. The band origins were also calculated. Numerous rotational perturbations observed in the A 1Π state in this molecule have been identified. The observed perturbations were confronted with those predicted from theoretical calculations. © 2012 IOP Publishing Ltd. pl_PL.UTF-8
dc.language.iso eng pl_PL.UTF-8
dc.publisher IOP Publishing ( Journal of Physics B: Atomic, Molecular and Optical Physics) pl_PL.UTF-8
dc.subject High resolution molecular spectroscopy pl_PL.UTF-8
dc.subject carbon monoxide
dc.subject rare12C17O isotopologue
dc.subject Ångström band system
dc.subject (B1Σ+ - A1Π)
dc.title Extended analysis of the Ångström band system (B1Σ+ - A1Π) in the rare12C17O isotopologue. pl_PL.UTF-8
dc.type article pl_PL.UTF-8

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